A recyclable CO surrogate in regioselective alkoxycarbonylation of alkenes: indirect use of carbon dioxide.
نویسندگان
چکیده
Herein, we report a Pd-catalysed alkoxycarbonylation of alkenes based on the use of a recyclable CO2 reduction product, the crystalline and air-stable N-formylsaccharin, as a CO surrogate. The carbonylation proceeds under ambient conditions in an exceptionally complementary regioselective fashion yielding the desired branched products from styrene derivatives and valuable linear esters from alkyl-substituted alkenes.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 63 شماره
صفحات -
تاریخ انتشار 2015